Zap the coast
By Northwestern University
An artistic impression of how electricity could be used to strengthen coastlines. Credit: Northwestern University |
In their study, recently published in Communications Earth and the Environment, the researchers took inspiration from clams, mussels, and other shell-dwelling sea life, which use dissolved minerals in seawater to build their shells.
Similarly, the researchers leveraged the same
naturally occurring, dissolved minerals to form a natural cement between
sea-soaked grains of sand. But, instead of using metabolic energy like mollusks
do, the researchers used electrical energy to spur the chemical reaction.
In laboratory experiments, a mild electrical current
instantaneously changed the structure of marine sand, transforming it into a
rock-like, immovable solid. The researchers are hopeful this strategy could
offer a lasting, inexpensive, and sustainable solution for strengthening global
coastlines.
“Over 40% of the world’s population lives in coastal areas. Because of climate change and sea-level rise, erosion is an enormous threat to these communities. Through the disintegration of infrastructure and loss of land, erosion causes billions of dollars in damage per year worldwide. Current approaches to mitigate erosion involve building protection structures or injecting external binders into the subsurface,” said Alessandro Rotta Loria, Louis Berger Assistant Professor of Civil and Environmental Engineering at Northwestern’s McCormick School of Engineering, who led the study.
“My aim was to develop an approach capable of changing the
status quo in coastal protection — one that didn’t require the construction of
protection structures and could cement marine substrates without using actual
cement. By applying a mild electric stimulation to marine soils, we
systematically and mechanistically proved that it is possible to cement them by
turning naturally dissolved minerals in seawater into solid mineral binders — a
natural cement.”
Challenges in Current Coastal Defense Strategies
From intensifying rainstorms to rising sea levels, climate
change has created conditions that are gradually eroding coastlines. According
to a 2020 study by the European Commission’s Joint Research Centre, nearly 26% of the Earth’s
beaches will be washed away by the end of this century.
To mitigate this issue, communities have implemented two
main approaches: building protection structures and barriers, such as sea
walls, or injecting cement into the ground to strengthen marine substrates,
widely consisting of sand. However, multiple problems accompany these
strategies. Not only are these conventional methods extremely expensive, but
they also do not last.
“Sea walls, too, suffer from erosion,” Rotta Loria said.
“So, over time, the sand beneath these walls erodes, and the walls can
eventually collapse. Oftentimes, protection structures are made of big stones,
which cost millions of dollars per mile. However, the sand beneath them can
essentially liquify because of a number of environmental stressors, and these
big rocks are swallowed by the ground beneath them.
“Injecting cement and other binders into the ground has a
number of irreversible environmental drawbacks. It also typically requires high
pressures and significant interconnected amounts of energy.”
Eco-Friendly Electrocementation Process
To bypass these issues, Rotta Loria and his team developed a
simpler technique, inspired by coral and mollusks. Seawater naturally contains
a myriad of ions and dissolved minerals. When a mild electrical current (2 to 3
volts) is applied to the water, it triggers chemical reactions. This converts
some of these constituents into solid calcium carbonate — the same mineral
mollusks use to build their shells. Likewise, with a slightly higher voltage (4
volts), these constituents can be predominantly converted into magnesium
hydroxide and hydromagnesite, a ubiquitous mineral found in various stones.
When these minerals coalesce in the presence of sand, they
act like glue, binding the sand particles together. In the laboratory, the
process also worked with all types of sands — from common silica and calcareous
sands to iron sands, which are often found near volcanoes.
“After being treated, the sand looks like a rock,” Rotta
Loria said. “It is still and solid, instead of granular and incohesive. The
minerals themselves are much stronger than concrete, so the resulting sand
could become as strong and solid as a sea wall.”
While the minerals form instantaneously after the current is
applied, longer electric stimulations garner more substantial results. “We have
noticed remarkable outcomes from just a few days of stimulations,” Rotta Loria
said. “Then, the treated sand should stay in place, without needing further
interventions.”
Sustainable Applications and Future Prospects
Rotta Loria predicts the treated sand should keep its
durability, protecting coastlines and property for decades. He also says there
is no need to worry about negative effects on sea life. The voltages used in
the process are too mild to feel. Other researchers have used similar processes
to strengthen undersea structures or even restore coral reefs. In those
scenarios, no sea critters were harmed.
If communities decide they no longer want the solidified
sand, Rotta Loria has a solution for that, too, as the process is completely
reversible. When the battery’s anode and cathode electrodes are switched, the
electricity dissolves the minerals — effectively undoing the process.
“The minerals form because we are locally raising the pH of
the seawater around cathodic interfaces,” Rotta Loria said. “If you switch the
anode with the cathode, then localized reductions in pH are involved, which
dissolve the previously precipitated minerals.”
The process offers an inexpensive alternative to
conventional methods. After crunching the numbers, Rotta Loria’s team estimates
that his process costs just $3 to $6 per cubic meter of electrically cemented
ground. More established, comparable methods, which use binders to adhere and
strengthen sand, cost up to $70 for the same unit volume.
Research in Rotta Loria’s lab shows this approach can also
heal cracked reinforced concrete structures. Much of the existing shoreside
infrastructure is made of reinforced concrete, which disintegrates due to
complex effects caused by sea-level rise, erosion, and extreme weather. If
these structures crack, the new approach bypasses the need to rebuild the
infrastructure fully. Instead, one pulse of electricity can heal potentially
destructive cracks.
“The applications of this approach are countless,” Rotta
Loria said. “We can use it to strengthen the seabed beneath sea walls or
stabilize sand dunes and retain unstable soil slopes. We could also use it to
strengthen protection structures, marine foundations, and so many other things.
There are many ways to apply this to protect coastal areas.”
Next, Rotta Loria’s team plans to test the technique outside
of the laboratory and on the beach.
Reference: “Electrodeposition of calcareous cement from
seawater in marine silica sands” by Andony Landivar Macias, Steven D. Jacobsen
and Alessandro F. Rotta Loria, 22 August 2024, Communications Earth
& Environment.
DOI:
10.1038/s43247-024-01604-3
The study was supported by the Army Research Office (grant
number W911NF2210291) and Northwestern’s Center for Engineering Sustainability
and Resilience.